Авторы: Fabian K.

2006 г.

Phys.Earth Planet.Int.

Young mid-ocean ridge basalts contain titanomagnetite crystals of varying size and composition. Many studies of their hysteresis properties have found Mrs/Ms ratios considerably above the theoretical limit of 0.5 for uniaxial single domain particles. Since titanomagnetite is a cubic mineral, high Mrs/Ms could occur due to cubic anisotropy which allows for Mrs/Ms values up to 0.866. On the other hand, titanomagnetites with high Ti content possess extremely large magnetostriction constants. Already slight internal stress easily outweighs cubic anisotropy and enforces uniaxial behavior. Are high Mrs/Ms ratios now a proof for very low internal stress? No! On the contrary, previous studies on synthetic titanomagnetite with high Mrs/Ms show that after annealing this ratio decreases. A possible explanation is that insufficient saturation of the hysteresis loop, used to infer Mrs/Ms, leads to underestimation of Ms. Here, a systematic experimental study on a young mid-ocean ridge basalt using fields of up to 7 T demonstrates that indeed the Mrs/Ms ratio of the single domain fraction does not significantly deviate from the theoretical value of 0.5 for uniaxial anisotropy. It is further estimated that internal stress above 200 MPa is necessary to explain the observed hysteresis behavior – a value which is consistent with recent independent approximations. On the other hand, theoretical loops for cubic minerals do not fit the observed data. In order to assess the validity of Ms determinations from hysteresis measurements, an improved method to evaluate the approach to saturation behavior of hysteresis loops is developed. It allows to recognize insufficiently saturated loops and thereby helps to avoid misinterpretation of standard Mrs/Ms measurements when high fields are not accessible

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