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High crystallinity Si-ferrihydrite: An insight into its Neel temperature and size dependence of magnetic properties.
Авторы: Berquo T., Banerjee S., Ford R.
2007 г.
JGR, Solid Earth
Ferrihydrite, an antiferromagnetic iron oxyhydroxide with resulting magnetization due to uncompensated spins, is of great importance for the cycling of many trace metals in the environment. Four ferrihydrite samples prepared with 1.3 to 3.5 wt% of Si at different synthesis temperatures (7.5C, 22C, 50C, and 75C) were studied by temperaturedependent hysteresis loops, ZFC/FC susceptibility curves, ac susceptibility and Mo¨ssbauer spectroscopy. The incorporation of Si into the ferrihydrite during synthesis changed the properties of this mineral. Interestingly, seven sharp lines were observed in the X-ray diffraction pattern of the ferrihydrite samples prepared at 50C and 75C. In general, both XRD and magnetism demonstrate that particle size decreased (from 23 nm to 2 nm) and particle size distribution narrowed as the synthesis temperature was lowered. Those samples prepared between 7.5C and 50C showed the expected superparamagnetic behavior of ferrihydrite below 300 K. The ferrihydrite prepared at 75C was unusually coarse-grained and had a blocking temperature above 300 K. Extrapolation of induced magnetization from the largest particles with the highest crystallinity allowed an estimate of a ferrihydrite Ne´el temperature of around 422 K. We also present XRD and magnetic data from large natural Si-ferrihydrite collected from a marine shallow-water hydrothermal area that formed at a temperature of approximately 88C.
Файл: 345.pdf
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