An enigma in rock magnetism: can microstructures in magnetite cause a threefold increase in the efficiency of NRM acquisition in the Stardalur Basalts?
Авторы: McEnroe S., Church N., Fabian K. et al
2022 г.
Geophys.J.Int.
Quaternary lavas of the Stardalur Caldera, 20 km northeast of Reykjavik, Iceland, create a
27 300 nT magnetic anomaly visible in both ground and aeromagnetic surveys. Here, we
provide a comprehensive mineralogical and rock magnetic data set to analyse NRM intensities
and Koenigsberger ratios of 57 drill-core samples from the critical zone (CZ) of the anomaly
high at depths between 41 and 131 m. This extends previous studies and verifies that the
anomaly is due to an unusually high intensity of remanent magnetization carried by magnetite.
The NRM of the CZ samples was acquired during the Olduvai subchron in a field of at most
today’s strength. NRM intensities range from 20 to 128 A m–1 with amedian of 55 A m–1, and an
average of 61 A m–1, respectively, approximately 13–15 times higher than in typical Icelandic
basalts (AIB) with an NRM intensity of 4 A m–1. Our new data set shows that the magnetite
concentration throughout the CZ basalts is at most twofold higher than in AIB lavas. New
data on domain state and TRM efficiency prove that these properties account for an additional
factor of at most 2.3. Because magnetite is the most abundant remanence carrier in rocks on
Earth, and its remanence acquisition is considered to be extremely well understood, we assert
that the remaining discrepancy is a critical enigma in rock magnetism. Results from scanning
electron microscopy show that a significant fraction of all CZ magnetite particles have dendritic
shapes with grain sizes <1 μm, indicating rapid crystallization. Most large magnetite grains
are heavily subdivided by very fine oxidation-exsolution lamellae of ilmenite, and subordinate
amount of exsolved spinel as needles, blebs and blades. These common microstructures found
throughout the CZ subdivide the initially homogeneous mineral into separate cubicles, here
denoted as compartments. The magnetite compartments then have sizes below 1μm. Hysteresis
data, Preisach maps and FORC data consistently confirm that the coercivity distribution is
dominated by values above 10 mT, such that multidomain behaviour is of little relevance in
the CZ. Between 5 and 20 per cent of the IRM is carried by coercivities above 100 mT, which
for magnetite indicates unusually high anisotropy effects in the individual particles. Based
on the quantitative analysis of all magnetic contributions to the NRM, we can demonstrate
that the average efficiency of NRM acquisition in the CZ Stardalur basalts must be at least a
factor 3 higher than in typical basalts. We speculate that this is related to the observed focused
compartment size distribution <1 μm, and indicates thermochemical remanence acquisition
below the Curie temperature of magnetite. Yet, a detailed physical mechanism for the extreme
overefficiency of NRM acquisition remains enigmatic.
Файл: 1079.pdf
|